Chemical Formulas

I.  Symbols and Elements
    A.  Names of Elements
        Planets:               People:                 Places:
         Mercury             Curium                 Europium
         Uranium            Einsteinium         Francium
         Plutonium         Mendelevium        Americium
                                   Lawrencium          Berkelium
                                                                 Californium
    B.  Symbols for Elements
         1.  chemical symbol:  short-hand representation of an element
         2.  J.J. Bezerlius:  Swedish chemist given credit for creating the modern
                                     symbols for elements.
         3.  Use first letter of elements name.  For two elements with the same first
              letter, the second letter or another important letter is added.  In some
              cases, the Latin name is used.

             Ex.  S - Sulfur        Se - Selenium    Sr - Strontium    Na - Sodium (Latin for
                                                                                                   Natrium)

        4.  Scientists in both the U.S. and Russia claim the discovery of elements 104
            and 105.  They couldn't decide on a name; therefore, the IUPAC
            (International Union of Pure and Applied Chemistry) adopted a system for
            naming the rest of the elements.

    C.  Use of Symbols
        1.     3216S    32 - mass #    16 - atomic #

        2.  Ion:  a charged atom
            a.  positive ion - loses electrons
            b.  negative ion - gains electrons
    D.  Chemical Formulas
          1.  combination of symbols that represents the composition of a compound
          2.  shows 2 things:
               a.  elements present
               b.  # of atoms of each element
 
 

Compound
Formula
Elements
ammonia
NH3
nitrogen, hydrogen
rust
Fe2O3
iron, oxygen
sucrose
C12H22O11
carbon, hydrogen, oxygen
table salt
NaCl
sodium, chlorine
water
H2O
hydrogen, oxygen

    E.  Oxidation Number
        1.  monotomic ion:  single atom takes a charge
                                      ex.  Cl-, O-2
        2.  oxidaton number:  charge on a monotomic ion
        3.  polyatomic ion:  ion made of more than one atom
                                    ex.  CO3-2, SO4-2, OH-
        4.  2 types of compounds
             a.  ionic compounds:  composed of ions; metal and non-metal
                                              ex. NaCl
             b.  molecular compounds:  neutral atoms formed from molecules;
                                                     non-metal and non-metal
                                                     ex.  H2O
                        -- diatomic molecules:  made of two atoms of the same element;
                                                          always found in nature as diatomic
 

Name
Formula
Bromine
Br2
Chlorine
Cl2
Fluorine
F2
Hydrogen
H2
Iodine
I2
Nitrogen
N2
Oxygen
O2

     5.  Writing Formulas for Ionic Compounds

          ex.  Ca+2   Br-      use subscripts to make the overall charge zero
                CaBr2

                 Al+3   SO4-2  =   Al2(SO4)3

                       Mg+2    O-2    =   MgO

II.  Nomenclature (Rules for Naming)
     A.  Naming Compounds
          1.  Binary Inorganic Compounds - contain only two elements
               a.  write the name of the element having the + charge
               b.  add the name of the negative element
               c.  name of the negative element must be modified to end in -ide
 

Formula
Name
 Al2S3
Aluminum Sulfide
 CaBr2
Calcium Bromide
 H2O
Hydrogen Oxide (water)
 H2Se
Hydrogen Selenide

 
 

            2.  Naming Binary Molecular Compounds
              -- use prefix and end in -ide
 

Prefix
# of atoms
mono
1
di
2
tri
3
tetra
4
penta
5
hexa
6
hepta
7
octa
8

              Examples:
 
 

Formula
Name
 CS2
carbon disulfide
 CO
carbon monoxide
 CCl4
carbon tetrachloride
 SF6
sulfur hexafluoride
 SO2
sulfur dioxide
 SO3
sulfur trioxide

    3.  Naming Compounds with Polyatomic Ions
        -- Name the element and end with negative ion name
 
 

Formula
Name
AlAsO4
Aluminum Arsenate
(NH4)2SO4
Ammonium Sulfate
ZnCO3
Zinc Carbonate
CuSO4 **
Copper (II) Sulfate
Cu2(SO4)3 **
Copper (III) Sulfate
                             ** variable oxidation states for transition metals

  4.  Naming Organic Compounds
 
 

# of carbon atoms
stem
1
meth
2
eth
3
prop
4
but
5
pent
6
hex
7
hept
8
oct
9
non
10
dec

                    ex.  CH4  -  methane
                          C2H-  ethane
                          C5H12 -  pentane

III.  Molecular and Empirical Formulas
       1.  molecular:  formulas for compounds that exist as molecules
                             ex.  H2O2  hydrogen peroxide
       2.  empircal:  simplest formula
                           ex.  H2O2 ---  HO
                                 C6H12O6 --- CH2O
       3.  coefficients:  used to represent the # of molecules or formula units of a
                                substance.
                                a.  molecules -- molecular compounds
                                b.  formula units -- ionic compounds